Author: nguyendun
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Electrochemical Alcohol Oxidation Reaction (AOR)
References 1. NonAqueous AOR 2. Aqueous AOR 2.1. References 2.2. Experiments 2.2.1. Preparing substrate 2.2.1. Preparing working electrode 2.2.3. Preparing electrolyte Electrolyte solutions used for oxygen evolution reaction (OER) experiments contained 1 M NaOH in water, and electrolyte solutions used for alcohol oxidation experiments (AOR) contained 1 M NaOH and 100 mM alcohol (EtOH, n-PrOH,…
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General Electrochemistry
References ElectroChemistry (EC) vs. PhotoElectroChemistry (PEC) In electrochemical N2 reduction, N2 reduction at the cathode is paired with water oxidation at the anode (Scheme 1a). The overall reaction is thermodynamically uphill, and therefore, an electrochemical N2 reduction cell requires an electrical energy input as in the case of an electrochemical water splitting cell. A photoelectrochemical…
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Preparation for Characterization
1. References 2. Brunaeur−Emmet−Teller (BET) The oxide samples were heated at 150 °C for 8–12 h to remove impurities, then immediately weighed, and transferred to the sample tube for measurement. The surface area was calculated with the Brunauer–Emmett–Teller (BET) method in the relative pressure range of 0.005–0.25 of adsorption data.[ACS Catal. 2023, 13, 1, 515–529]…
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Prepare working electrode
References 1. NonAqueous NITRR 2. Aqueous NITRR 2.1. References 2.2. For Electrochemical Catalyst 2.2.1. Preparing working electrode Material loaded on carbon cloth (1.0×1.0 cm2) were used as the working electrode. For the preparation of catalysts loaded on carbon cloth, the carbon cloth was first ultrasonically cleaned for several times in alternative baths of deionized water…
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Nitrate Reduction to Ammonia (NITRR)
References 1. NonAqueous NITRR 2. Aqueous NITRR 2.1. References 2.2. Experiments 2.2.3. Preparing electrolyte The electrocatalytic activities of WE for NITRR were tested in 0.1 M Na2SO4 (adjust to pH 11.5 using 1.0 M NaOH solution) with 0.1 M KNO3 under 25 °C and ambient pressure. Due to the presence of HER and NITRR during…
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Electrochemical Alcohol and Aldehyde Oxidation
References Keywords Rate Deconvolution Procedure J. Am. Chem. Soc. 2020, 142, 51, 21538–21547 Quantum-ESPRESSO J. Am. Chem. Soc. 2020, 142, 51, 21538–21547 Schematic Mechanism https://www.nature.com/articles/s41467-020-18461-1, https://pubs.acs.org/doi/full/10.1021/acscatal.1c04163 1. NonAqueous Electrolyte 2. Aqueous Electrolyte 2.1. References 2.2. Experiments Linear sweep voltammetry (LSV) was performed with a 3-electrode setup in an undivided cell made of glass. Ni(OH)2 films…
